This was 12.5 percent lower than the state average of 43.7 percent. In 2020 the total municipality population reached 591.
95 percent of the population had at least a high school diploma or the equivalent.
Degree distribution in St. Libory for 2020*
| Degree | Number of people | Percentage of population |
|---|---|---|
| No degree | 23 | 5 |
| Regular high school diploma | 124 | 26.7 |
| GED or alternative credential | 47 | 10.1 |
| Some college, less than 1 year | 66 | 14.2 |
| Some college, 1 or more years, no degree | 59 | 12.7 |
| Associate's degree | 63 | 13.6 |
| Bachelor's degree | 55 | 11.9 |
| Master's degree | 25 | 5.4 |
| Professional school degree | 2 | 0.4 |
| Doctorate degree | 0 | 0 |
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